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Home 9 Surface Finishing 9 What is Alodine Aluminum? Process, Advantages, and Examples

What is Alodine Aluminum? Process, Advantages, and Examples

Author: Yaozu Deng
Published on: 2024-10-12

“Alodine coating treatment is a highly preferred solution for industrial applications that demand durable, lightweight, and electrically conductive aluminum finishes.”

Secondary coating or plating in manufactured aluminum parts has been a popular method of finishing and customization of surface characteristics. Alodine aluminum refers to adding a permanent layer of chromium and other metal salts in minor amounts.  Moreover, Alodine® is a commercial brand name for chem film of chromate coating. 

The alodine coating can be different ways, but the end purpose is enhancing corrosion resistance and durability. The alodine layer acts as the barrier from exterior environmental conditions and protects the underlying aluminum substrate. 

Let’s discuss the process, methods, and use of alodine coating;

 

What is Aluminum Alodine Coating?

Alodine conversion coating involves the passivation of metal surfaces by developing a protective oxide layer( Al2​O3​⋅Cr2​O3​) that prevents corrosion, wear, material degradation, etc. Typically, processes are carried out with the alodine solution or sprays. 

This coating also maintains the dimensional stability of parts, the negligible thickness of the coating ( 0.00001-0.00004”) does not affect the accuracy. Moreover, alodine is also a good base for further painting or dyes. 

Consumer items, automotive parts, heat sinks, aircraft components, and various other applications apply the alodine coating to enhance performance and durability. 

Can I Coat Alodine in Other Metals Besides Aluminum?

Yes! Although alodine conversion coating is mostly popular for aluminum alloy parts, it can be used for other various metals and alloys. For instance, zinc, brass, copper, titanium, steel, etc. It can also provide corrosion resistance and adhesion for these types of metals. However, they might require additional treatments or layers to achieve comparable levels of protection. 

 

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Types of Aluminum Alodine Coating 

The alodine coating is divided into different types based on the composition of alodine solution and specific standards of finishing. The most common standard is MIL-DTL-5541. It has two main variations; Type I and Type II. 

Type I Alodine Coating

It is a MIL-DTL-5541 standard finish that gives a clear or golden brown aesthetic to aluminum parts. Chemically, Type I alodine or chromate conversion coating is characterized by the presence of hexavalent chrome. 

However, it is considered a relatively hazardous coating than type II. So, alodine Type I aluminum coating can be restricted for some sensitive applications. 

Type II Alodine Coating 

Type II does not contain hexavalent chromium. Instead, it relies on trivalent chrome. This type of chemical conversion coating aluminum also complies with the  MIL-DTL-5541. It provides enhanced resistance to corrosion compared to a type I alodine finish. Other benefits include less– time-consuming, electrical conductivity, and a low-temperature process.

Type II is more common across industrial applications, it is used for protection and aesthetic. Moreover, it does not impose any risk of hazardous chemicals like type I. 

 

What are the Steps of the Aluminum Alodine Coating Process?

The alodine aluminum treatment process involves immersion or spraying the substrate aluminum components with a chromate-based solution. It triggers the reaction of chromate with aluminum, producing a thin chemical conversion coating layer.

Alodine coating setup

Here are the steps in brief;

Step 1: Substrate Cleaning 

First, thoroughly clean the aluminum substrate to remove debris, oils, grease, or any potential contamination. It is essential to ensure that the surface is free from any contaminations for stranger adhesion. 

Step 2: Surface Etching 

The chemical etching process makes the cleaned aluminum surface uniform and facilitates better coating. You can use chemicals like ferric chloride to etch the surface. Next, deoxidizing is also important to neutralize the inert oxygen or metal oxides present on the surface. 

Step 3: Submerging in Alodine Solution 

Dry the etched surface and submerge the aluminum parts into the alodine solution. Here immersion time and chrome ion concentration in the solution depends on the thickness and type of alodine coating.  Besides submerging in solution, spraying with automatic nozzles or manually can also coat the alodine. 

Step 4: Final Washing of Parts 

Once the coating is complete, eject the parts from the solution and wash them with warm water. Then, dry and inspect the parts for quality control before packaging.

 

Why Use Alodine Conversion Coating on Aluminum Parts?

Alodine can be applied on machined, fabricated, extruded, and casted aluminum parts and products to enhance corrosion resistance and make an adhesive foundation for painting. 

The following are the benefits of applying alodine coating;

Corrosion Resistance

The developed chromium layer not only protects from external environmental factors but also eliminates microscopic irregularities like pores, cracks, etc. The protective film acts as a barrier when exposed to harsh conditions. As a result, the aluminum parts become highly corrosion-resistant.

Room Temperature Process

The type II chemical conversion coating is carried out at room temperature, which makes it simple to operate. Also, it makes it easy to control the processing parameters like temperature fluctuation and immersion time. 

Primer for Painting 

The alodine aluminum acts as a good adhesion for painting. It strongly bonds the applied paints due to its uniformity and smoothness. Therefore, many applications use it as a primer for aesthetic painting. Eg.  aircraft body painting. 

Electrical Conductivity

Type II, class 3 alodine slightly improves the electrical properties of aluminum substrates. The negligible thickness of alodine does not cover the original electrical properties. Instead, it provides a smooth and uniform contact surface for electrical connectors.

 

Applications of Aluminum Alodine Finish

Alodine-coated aluminum parts

Aerospace 

The alodine film does not add weight and it protects the aircraft, satellite, and drone parts from extreme weather conditions. In many cases, the aerospace parts are subjected to an alodine finish before applying the painting. 

  • Exterior body parts 
  • Landing gear
  • Tail and wing surfaces
  • UAV frames
  • Avionics enclosures, etc. 

Defense and Military 

 MIL-DTL-5541 standard also complies with the manufacturing of military-grade aluminum components. Diverse military and defense items use it for finishing or foundation for paints and further plating. 

  • Armor panels
  • Armed vehicles
  • Gun barrel
  •  Radar system housings
  • Drone frames 

Electrical Components

Corrosion protection and better electrical contact surfaces are two main benefits of alodine aluminum in the electrical industry. 

  • Metal housings of electrical electronics products
  • Aluminum heat sinks 
  • Connecting wires
  • Circuit board shields
  • Mounting brackets

Automotive Industry

The alodine finish is applied to various vehicle components to avoid degradation due to corrosion and to apply strong and appealing aesthetic paints. 

  • Engine hoods
  • Chassis components
  • Radiator brackets
  • Body panel
  • Wheels
  • Suspension parts and casing 

Other Applications 

Other industries also use the alodine finish on aluminum parts. For example, architectural, decorative, renewable energy, and marine components.

  • Solar panel frame
  • Wind turbine blade supports
  • Power converter casings
  • Building architectural exteriors
  • Industrial & chemical processing equipment
  • Ships and offshore platform items

 

Alodine Coating vs. Anodizing

Unlike alodine, anodizing is an electrochemical process that develops a protective layer of aluminum oxide (Al₂O₃) on the surface, which acts as a natural barrier.  However, they both enhance the corrosion resistance. Additionally, anodized aluminum can be dyed into numerous color options and also improves the lubrication properties.

Anodizing vs alodine coating

The anodized surface contains microscopic pores on the surface, applying dyes and sealing helps to absorb the dyes into pores and results in a durable aesthetic. 

The table below shows the differences between alodine vs anodize aluminum parts;

Criteria Alodine Coating Anodizing
Process Chemical conversion process without electricity An electrochemical process that uses an electric current in an acid bath
Cost Economical for small-scale production It is suitable for medium to large-scale production
Corrosion Resistance Moderate to high corrosion resistance High corrosion resistance, especially in harsh environments
Electrical Conductivity It retains electrical conductivity Reduces electrical conductivity due to the oxide layer
Coloring Options Limited to clear or brown shades Wide range of colors available, best for aesthetics
Thickness Thin coating, minimal effect on part dimensions A thicker oxide layer might affect the tolerances
Applications Aerospace, electrical grounding, marine parts, etc. Aerospace, medical devices, consumer goods, automotive, etc.

 

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Get Alodine Coated Aluminum Parts from ProleanTech

Do you need aluminum parts with alodine chromate conversion finishes? Our factory has been working on finishing CNC machined, sheet metal, casting, and extrusion aluminum parts for more than a decade. We have advanced equipment for immersion and controlling the alodine coating variables.

We protect your aluminum parts with an alodine layer of less than 1 μm. Our engineers closely work with the clients to understand the requirements and deliver the expected results. So, if you need an alodine coating service, contact us today!

 

Conclusion 

Alodine coating is a popular finishing for aluminum parts across industries, from automotive components to military and defense items. Applying its layer enhances corrosion protection in harsh environments. Additionally, the alodine layer also serves as an excellent primer for further painting. You can use MIL-DTL-5541 type II or other specific standards to protect your parts over a long period. 

 

FAQs

Is chromate conversion coating the same as Alodine coating?

Yes, they are essential to the same processes. Alodine is a brand name for a popular type of chromate conversion coating solution. 

What is the functionality of an aluminum Alodine finish?

Alodine coating provides corrosion resistance to aluminum and enhances paint adhesion. It forms a protective layer on the surface with a high degree of dimensional stability. 

Are Alodine coated parts durable?

Alodine-coated parts offer moderate durability, especially in terms of corrosion resistance. However, they are not as wear-resistant as anodized finishes. 

How thick is the Alodine layer?

The Alodine layer is very thin, typically between 0.00001 to 0.00004 inches (0.25 to 1 micron). This thin layer allows it to protect the surface without affecting the dimensions or electrical conductivity of the part.

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